When we recite Duroo
When we recite Durood (Salawaat) we mention the Prophet Muhammad (SAWA) and his Progeny (Ahlul Bayt)(AS) and Hazrat Ali (AS) is the head of Ahlul Bayt (AS) after the Prophet (SAWA).
Imam Ali (AS) was brought in Mubahala as Nafs of the Prophet (SAWA) while Hasan (AS) and Husain (AS) where brought as the sons of the Prophet (SAWA).
Imam Redha (AS) when Al-Ma'moon asked him about he greatest tribute of Ali in Quran, said : Mubahala when Allah mentioned Ali as Nafs of the Prophet (SAWA).
Wassalam