Istekhara is seeking guidance from Allah (SWT) in any matter which is permissible in principle and we are unable to decide about it.
If you have already decided an action, there is no point in Istekhara after you have decided.
'Loving something does not mean that it is good for us. Millions of people suffered a lot from things which they loved sometime then discovered later that love was based on mirage not facts. Sensible persons do not rely on love only but on intellect and factual reasons. If you are not sure whether your love is based on facts or emotions, you can go for Istekhara to be guided.
Wassalam.